First Law of Thermodynamics

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First Law of Thermodynamics: Overview

This Topic covers sub-topics such as First Law of Thermodynamics, Enthalpy, Joule-Thomson Effect, Law of Equipartition of Energy, Limitations of First Law of Thermodynamics, Joule-Thomson Coefficient, Enthalpy of Reaction and, Throttling Process

Important Questions on First Law of Thermodynamics

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When 1 mol of a gas is heated at constant volume, temperature is raised from 298 to 380 K. If heat supplied to the gas is 500 J, then which statement is correct?

                               

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If ΔH is the change in enthalpy and ΔE, the change in internal energy accompanying a gaseous reaction, then

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Internal energy and pressure of a gas per unit volume are related as:

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Explain where the First Law of Thermodynamics failed.

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Which of the following is not explained by First Law of Thermodynamics?

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First Law of Thermodynamics failed to explain the direction of the convertibility of one form of energy into another.

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Amount of heat energy transferred from one system to another was explained by the First Law of Thermodynamics.

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What are the limitations of First Law of Thermodynamics?

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Define Joule-Thomson Coefficient.

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The Joule Thomson coefficient for an ideal gas is equal to _____(positive/zero/negative).

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The Joule Thomson coefficient for an ideal gas is positive.

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The Joule–Thomson coefficient μ is defined as the ratio of the volume change to the pressure drop, and is expressed in terms of the thermal expansion coefficient and the heat capacity.

 

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The Joule–Thomson coefficient μ is defined as the ratio of the temperature change to the _____ (pressure/volume) change, and is expressed in terms of the thermal expansion coefficient and the heat capacity.

 

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Using Joule-Thomson Effect describe what happens to the temperature of a gas when throttled through an orifice.

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During Joule-Thomson effect, the volume of gas in decreased when throttled through an orifice.

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During Joule-Thomson effect, the _____ of gas in decreased when throttled through an orifice.

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What are the conclusions of Joule-Thomson effect?

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What happens during Joule-Thomson effect?

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Explain Joule–Thomson effect.

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Which of the following effect deals with the change in the temperature of a real gas or a liquid when allowed to expand freely through a valve or other throttling device?